From SmashWiki, the Super Smash Bros. wiki
Triple Finish is Pokémon Trainer's Final Smash. After one of his Pokemon grab a Smash Ball, Pokemon Trainer sends out his other Pokemon to join the first in a powerful triple attack. This attack sends out multiple elemental Pokemon techniques(Hydro Pump, Solar Beam, and Fire Blast), which cover an extremely large area. Any enemy caught in the attack suffer major damage; the closer they are to the Pokemon, the more damage received. After the attack is finished, all opponents effected are sent flying. During this attack, a text box appears at the bottom of the screen, which is filled with sentences like "It's super effective!"
Gallery
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Final Smashes
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 The Mighty Jinjonator ·  Infernal Climax ·  Giga Bowser (  ), Giga Bowser Punch ( ) ·  Shadow Mario Paint ·  Progenitor God Ruptured Heaven ·  Blue Falcon ·  Mega Evolution (Charizard) () ·  Awakening Aether ·  Omnislash (), Omnislash / Omnislash Ver. 5 () ·  Torrential Roar ·  Daisy Blossom ·  Dark Pit Staff ·  Phazon Laser ·  Rocketbarrel Barrage (), Hyper Rocketbarrel () ·  Konga Beat (), Jungle Rush () ·  Doctor Finale ·  NES Zapper Posse ·  Landmaster (), Team Star Fox () ·  Landmaster (), Team Star Fox () ·  Beast Ganon (), Ganon, The Demon King () ·  Secret Ninja Attack ·  Gigaslash ·  Iceberg ·  Great Aether ·  Max Malicious Moonsault ·  Killer Wail ·  Dream Town Hall ·  Puff Up ·  All-Out Attack ·  Final Blaster ·  Shippu Jinraikyaku / Shinryuken ·  Waddle Dee Army (), Dedede Burst (), Dede-Rush () ·  Blast-o-Matic ·  Cook Kirby (), Ultra Sword () ·  Triforce Slash (), Ancient Bow and Arrow () ·  Giga Mac (), Giga Mac Rush () ·  Aura Storm (), Mega Evolution (Lucario) () ·  PK Starstorm ·  Critical Hit ·  Negative Zone (), Poltergust 5000 (), Poltergust G-00 () ·  Mario Finale ·  Critical Hit ·  Mega Legends ·  Galaxia Darkness (), Darkness Illusion () ·  Psystrike ·  Omega Blitz ·  Full Blast ·  Final Edge ·  ARMS Rush ·  Octopus ·  Sacred Arrow ·  PK Starstorm ·  End of Day ·  Super Pac-Man ·  Black Hole Laser ·  Peach Blossom ·  Volt Tackle ·  Volt Tackle ·  Petey Piranha ·  Palutena's Army (), Three Sacred Treasures (), Lightning Chariot () ·  Triple Finish ·  Burning Sword ·  Grand Cross ·  Plasma Scream ·  Diffusion Beam (), Super Diffusion Beam (), Guided Robo Beam () ·  Pair Up ·  Power Star (), Grand Star () ·  Critical Hit ·  Shin Shoryuken / Shinku Hadoken ·  Zero Laser ·  Supernova ·  Light Arrow (), Sheikah Dance () ·  Chain Attack ·  Grand Cross ·  Grenade Launcher (), Covering Fire () ·  Super Sonic ·  Sealing the Keyhole ·  House of Boom ·  Triple Wolf ·  Triforce Slash ·  Dream Home ·  Wario-Man ·  Wii Fit ·  Landmaster (), Team Star Wolf () ·  Super Dragon (), Stampede! () ·  Triforce Slash ·  Light Arrow (), Triforce of Wisdom () ·  Power Suit Samus (), Gunship (), Zero Laser ()
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I think it's not always super effective, but am not sure. I also think some things depend on what pokemon gets the smashball, but am still not sure. Anyone is welcome to test it out!
